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Based on the simulative results, exergetic analysis of the whole process is performed to optimize the overall exergetic efficiency.

The results indicate that the exergetic efficiency is improved slightly with a decrement in the system pressure drop. Compared to other conversion technologies, biomass to liquid fuel conversion via fast pyrolysis and subsequent hydrodeoxygenation has higher exergetic efficiency.

Segmented catalytic co-pyrolysis of biomass and high-density polyethylene for aromatics production with MgCl 2 and HZSM For the catalytic co-pyrolysis of glucose and high-density polyethylene HDPE in a fixed-bed reactor, the effects of different layout schemes of feedstock and catalysts on bio-oil yield and aromatics selectivity were investigated based on the Diels-Alder reaction of furans and short-chain olefins on HZSM-5 for aromatics production.

A mixture of pine sawdust and MgCl2 as a glucose substitute that provided furan compounds Furfural reacted with short-chain olefins for aromatics production.

The effects of co-pyrolysis temperature, biomass to HDPE ratio, and feedstock to catalyst ratio on bio-oil yield and chemical compositions were discussed.

Notably, an appropriate ratio between the amounts of furans and short-chain olefins is necessary for increasing bio-oil yield and aromatics selectivity.

Maximum oil phase product yield of Deactivation of zeolite catalysts due to coke deposition is a pronounced challenge in the hydrodeoxygenation HDO of bio-oil.

Application of Aspen Plus in thermal conversion of biomass into liquid fuels: This paper presents a review on the reported studies by using Aspen Plus to simulate the processes involved in biomass fast pyrolysis for liquid fuels.

It can be divided into two parts of the study: The reaction research is less,but it can also prove that Aspen Plus can be used to simulate the chemical reaction.

Most research focused on the simulation of the whole process, and analyze the economic, environmental, and energy consumption of the whole process.

The maj or problems in the field are listed and the future development of research is also prospected. The conversion of biomass into high quality liquid fuels via fast pyrolysis and subsequent hydrogenation is introduced.

The amount of carbon compounds with two oxygen atoms is decreased with increasing reaction temperature due to their splitting by activated H2 during HDO processing of bio-oil.

Carbon compounds with one oxygen atom are changed during the HDO of bio-oil processing, where soluble carbon compounds were converted to insoluble ones, with increasing reaction temperature leading to increase in hard carbon compounds.

The related mechanism is presented in the paper. The composition of soluble coke was obtained by gas chromatography-mass spectrometry GC-MS measurements.

It is found that coke can be divided into soft coke, hard coke, and graphite at different reaction temperatures. Organic reactants can be transformed into soft coke and hard coke by different chemical reactions, such as alkylation, aromatization, hydrogen transfer, and dehydrogenation.

These catalysts were characterized by X-ray diffraction, N2 physisorption, and scanning electron microscope, respectively.

The effect of catalyst type on carbon conversion and hydrogen yield was determined. The catalyst can be sustained for 70 h without deactivation.

Bio-oil produced from prolysis process of biomass cannot be directly used for transportation fuels, because of the poor quality.

Catalytic hydrogenation is then used to upgrade bio-oil to engine-grade fuel. However, external H2 addition may not be cost effective to obtain high quality of oil.

In this work, the feasibility of in situ hydrogen generation and hydrodeoxygenation is studied. Formic acid and acetic acid were selected as compounds for hydrogen generation by reforming reaction.

The amount of H2 generation depended on the type of catalyst and substrate used. For example, 1 mol formic acid yielded 0.

The Furfural and phenol could be hydrogenrated and translated to different byproducts with in situ generated H2, with some byproducts identified.

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Deactivation of zeolite catalysts due to coke deposition is a pronounced challenge in the hydrodeoxygenation HDO of bio-oil.

Application of Aspen Plus in thermal conversion of biomass into liquid fuels: This paper presents a review on the reported studies by using Aspen Plus to simulate the processes involved in biomass fast pyrolysis for liquid fuels.

It can be divided into two parts of the study: The reaction research is less,but it can also prove that Aspen Plus can be used to simulate the chemical reaction.

Most research focused on the simulation of the whole process, and analyze the economic, environmental, and energy consumption of the whole process.

The maj or problems in the field are listed and the future development of research is also prospected. The conversion of biomass into high quality liquid fuels via fast pyrolysis and subsequent hydrogenation is introduced.

The amount of carbon compounds with two oxygen atoms is decreased with increasing reaction temperature due to their splitting by activated H2 during HDO processing of bio-oil.

Carbon compounds with one oxygen atom are changed during the HDO of bio-oil processing, where soluble carbon compounds were converted to insoluble ones, with increasing reaction temperature leading to increase in hard carbon compounds.

The related mechanism is presented in the paper. The composition of soluble coke was obtained by gas chromatography-mass spectrometry GC-MS measurements.

It is found that coke can be divided into soft coke, hard coke, and graphite at different reaction temperatures. Organic reactants can be transformed into soft coke and hard coke by different chemical reactions, such as alkylation, aromatization, hydrogen transfer, and dehydrogenation.

These catalysts were characterized by X-ray diffraction, N2 physisorption, and scanning electron microscope, respectively. The effect of catalyst type on carbon conversion and hydrogen yield was determined.

The catalyst can be sustained for 70 h without deactivation. Bio-oil produced from prolysis process of biomass cannot be directly used for transportation fuels, because of the poor quality.

Catalytic hydrogenation is then used to upgrade bio-oil to engine-grade fuel. However, external H2 addition may not be cost effective to obtain high quality of oil.

In this work, the feasibility of in situ hydrogen generation and hydrodeoxygenation is studied. Formic acid and acetic acid were selected as compounds for hydrogen generation by reforming reaction.

The amount of H2 generation depended on the type of catalyst and substrate used. For example, 1 mol formic acid yielded 0. The Furfural and phenol could be hydrogenrated and translated to different byproducts with in situ generated H2, with some byproducts identified.

The results provide a clear rationale for utilization of in situ generated H2 for future bio-oil upgrading to reduce external H2 usage.

Role of the Solvent. The results clearly demonstrated that the use of a supercritical solvent resulted in an upgraded product with improved properties compared to upgraded bio-oil using no solvent or subcritical solvent conditions.

These improvements included a decrease in oxygen content from The most important improvement is that carbon deposition was limited to only 0.

Thus, coking was overcome effectively during the upgrading process. The solvent played several roles: The reaction pathways in supercritical bio-oil upgrading primarily include esterification, etherification, acetalization, hydrogenation, and hydrodeoxygenation.

In this study, the properties of upgraded bio-oil purified via vacuum distillation to remove the solvent were quantified. Ocean freight imports going back to November Our Limited Plan lets you monitor the shipping activities of any three companies across all our databases.

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Chat Live Now No, thanks. Our bill of lading data reveals the trading activities of Hangzhou Changsen Hardware Co Ltd and millions of other manufacturers.

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